Fluorosurfactants

ABSTRACT

The present invention relates to the use of end groups Y, where Y stands for CF 3 O— or F 5 S—, as hydrophobic end group in surface-active compounds, corresponding novel compounds, and processes for the preparation of these compounds.

The present invention relates to the use of end groups Y, where Y standsfor CF₃O— or F₅S—, as hydrophobic end group in surface-active compounds,corresponding novel compounds, and processes for the preparation ofthese compounds.

Fluorosurfactants have an outstanding ability to lower the surfaceenergy, which is utilised, for example, in the hydrophobicisation ofsurfaces, such as textile impregnation, the hydrophobicisation of glassor the de-icing of air-craft wings.

In general, however, fluorosurfactants contain perfluoroalkylsubstituents, which are degraded in the environment by biological andother oxidation processes to give perfluoroalkanecarboxylic acids and-sulfonic acids. These are regarded as persistent and are in some casessuspected of causing health problems (G. L. Kennedy, Jr., J. L.Butenhoff, G. W. Olsen, J. C. O'Connor, A. M. Seacat, R. G. Perkins, L.B. Biegel, S. R. Murphy, D. G. Farrar, Critical Reviews in Toxicology2004, 34, 351-384). In addition, relatively long-chainperfluoroalkanecarboxylic acids and -sulfonic acids accumulate in thefood chain.

There is therefore a demand for surface-active substances having aproperty profile which is comparable to the classical fluorosurfactants,but which do not leave behind any persistent organofluorine degradationproducts on oxidative or reductive degradation.

The Omnova company markets polymers whose side chains have terminal CF₃or C₂F₅ groups. International patent application WO 03/010128 describesperfluoroalkyl-substituted amines, acids, amino acids and thioetheracids which have a C₃₋₂₀-perfluoroalkyl group.

JP-A-2001/133984 discloses surface-active compounds havingperfluoroalkoxy chains which are suitable for use in antireflectioncoatings. JP-A-09/111286 discloses the use of perfluoropolyethersurfactants in emulsions.

However, all fluorosurfactants disclosed hitherto ultimately result ondegradation, in the formation of persistent perfluoroalkanesulfonicacids and -carboxylic acids. Even the substitutes having a terminal CF₃group which were introduced as being more ecologically compatible can bedegraded to give persistent trifluoroacetic acid. There thereforecontinues to be a demand for further, fully degradable substitutes forperfluorinated surfactants.

It has now been found that compounds which carry at least one terminalpentafluorosulfuranyl group or at least one terminal trifluoromethoxygroup and have a polar end group are surface-active and are highlysuitable as surfactants.

The present invention therefore relates firstly to the use of end groupsY, where Y stands for CF₃O— or F₅S—, as hydrophobic end group insurface-active compounds.

The end group Y in the surface-active compounds is preferably bonded toa saturated or unsaturated, branched or unbranched hydrocarbon unit. Thehydrocarbon units may be aliphatic or aromatic units, optionallyprovided with hetero atoms.

Besides the said fluorinated end groups, the compounds to be used inaccordance with the invention preferably contain no further fluorinatedgroups.

In a variant of the invention, the end group Y occurs a number of timesin the surface-active compound and the surface-active compound ispreferably an oligomer or polymer.

In another, likewise preferred variant of the invention, the end group Yonly occurs once, twice or three times in the surface-active compound,where compounds in which the end group only occurs once are particularlypreferred. The compounds to be used in accordance with the invention arepreferably low-molecular-weight compounds of the formula IY-spacer-X  Iwhere

-   -   Y stands for CF₃O— or F₅S—,    -   spacer stands for a saturated or unsaturated, branched or        unbranched hydrocarbon unit,    -   X stands for a cationic, nonionic, amphoteric or anionic polar        group or a polymerisable group.

It is particularly preferred here for the compound of the formula I tobe selected from the compounds of the formulae Ia, Ib and IcY—(CH₂)_(n)—X  IaY—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IbY—CH═CH—(CH₂)_((n−1))—X  Icin which Y stands for CF₃O— or F₅S—,

-   -   n stands for an integer from the range 1 to 30 and    -   X stands for a cationic, nonionic, amphoteric or anionic polar        group or a polymerisable group,        (Hal) stands for F, Cl, Br or I,        and corresponding salts of the compounds of the formula Ia, Ib        or Ic.

Very particular preference is given here to the use of compounds of theformula Ia where n particularly preferably stands for an integer fromthe range 4 to 24 and especially preferably an integer from the range 6to 18. In a variant of the invention, it is in turn preferred for n tobe an even number.

Particular preference is given in accordance with the invention to theuse of the above-mentioned compounds as surfactants.

If the compounds of the formula I are anionic compounds or compoundswhich can be converted into anions of salts, it is preferred for thecounterion to be an alkali metal ion, preferably Li⁺, Na⁺ or K⁺ analkaline earth metal ion or NH₄ ⁺. If the compounds of the formula I arecationic compounds or compounds which can be converted into cations ofsalts, it is preferred for the counterion to be a halide, such as Cl⁻,Br⁻ or I⁻, or CH₃SO₃ ⁻, CF₃SO₃ ⁻, CH₃PhSO₃ ⁻ or PhSO₃ ⁻.

Some corresponding or structurally similar compounds are known from theliterature:

-   -   The Beilstein database (Beilstein Institut zur Förderung der        chemischen Wissenschaften; 2003) describes, inter alia, the        compounds 2-(pentafluorosulfuranyl)ethanol,        carboethoxymethylsulfur pentafluoride,        pentafluorosulfuranylacetic acid and        pentafluorosulfuranylethanesulfonic acid.    -   The preparation of pentafluorosulfuranylacetaldehyde and        pentafluorosulfuranylacetic acid is described in N. H. Ray, J.        Chem. Soc., Abstracts 1963, 1440, or GB 941.392 and GB 941,393.        U.S. Pat. No. 3,102,903 describes the preparation of various        pentafluorosulfuranylacetic acid derivatives.    -   Orthocarbonates and carbamates of pentafluorosulfuranylethanol        having nitro end groups and the use thereof as explosive are        described in U.S. Pat. No. 4,849,540.    -   A. F. T. Yokochi, R. Winter, G. Gard, Acta Cryst. 2002, E58,        o1133-o1135 discloses the crystal structure of        3-pentafluorosulfuranylpropionic acid.    -   The preparation of various 3-pentafluorosulfuranylpropane        derivatives is described in R. Winter, G. L. Gard, J. Fluorine        Chem. 2000, 102, 79-87. Reaction of SF₅Br with acrylic acid        esters and subsequent modification of the ester group gives        3-pentafluorosulfuranylpropionic acid,        3-pentafluorosulfuranylpropanol and        3-bromo-1-pentafluorosulfuranylpropane.    -   Pentafluorosulturanylmethanesulfonates SF₅CX₂SO₃ where X═H or F        are described in B. H. Ward, J. A. Schlueter, U. Geiser, H. H.        Wang, E. Morales, J. P. Parakka, S. Y. Thomas, J. M.        Williams, P. G. Nixon, R. W. Winter, G. L. Gard, H.-J. Koo,        M.-H. Whangboo, Chem. Mater. 2000,12, 343-351.    -   Pentafluorosulfuranylethanesulfonate is described in J. P.        Canselier, J. L. Boyer, V. Castro, G. L. Gard, J.        Mohtasam, D. H. Peyton, Magn. Reson. Chem. 1995, 33, 506-510.    -   R. Winter, G. I. Gard, J. Fluorine Chem. 1994, 66, 109-116        describes the preparation of various esters of        pentafluorosulfuranylethanols and -propanols.    -   WO 2004/011422 describes the preparation of aliphatic and        aromatic compounds having pentafluorosulfuranyl substituents.        The preparation is carried out by the addition reaction of SF₅CI        onto double bonds. For example, compounds of the        F₅S—CH₂—CHCl—(CH₂)₈—X¹ type, where X¹ stands for OH, OC(═O)CH₃,        Br, C(═O)OC₂H₅ or C(═O)CH₃, are prepared.

Advantages of the compounds according to the invention or use accordingto the invention of the said compounds or the compositions according tothe invention may be, in particular:

-   -   a surface activity which is superior to that of conventional        hydrocarbon surfactants with respect to efficiency and/or        effectiveness,    -   biological and/or abiotic degradability of the substances        without the formation of persistent, perfluorinated degradation        products,    -   good processing properties in formulations,    -   storage stability.

The present invention furthermore relates to the corresponding novelcompounds of the formula I, in particular compounds of the formula IIa,IIb or IIcCF₃O—(CH₂)_(n)—X  IIaCF₃O—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IIbCF₃O—CH═CH—(CH₂)_((n−1))—X  IIc

-   -   in which    -   n stands for an integer from the range 1 to 30 and    -   X stands for a cationic, nonionic, amphoteric or anionic polar        group or a polymerisable group,    -   (Hal) stands for F, Cl, Br or I,        and corresponding salts of the compounds of the formula IIIa,        IIIb or IIIc, where CF₃—O—CH₂—COOH is excluded,        and compounds of the formula IIIa, IIIb or IIIc        F₅S—(CH₂)_(n)—X  IIIa        F₅S—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IIIb        F₅S—CH═CH—(CH₂)_((n−1))—X  IIIc    -   in which    -   n stands for an integer from the range 1 to 30 and    -   X stands for a cationic, nonionic, amphoteric or anionic polar        group or a polymerisable group,    -   (Hal) stands for F, Cl, Br or I,    -   corresponding salts of the compounds of the formula IIIa, IIIb        or IIIc, where the compounds. F₅S—(CH₂)₁—CO₂M, F₅S—(CH₂)₂—CO₂M,        F₅S—(CH₂)₁—SO₃M, F₅S—(CH₂)₂—SO₃M, F₅S—(CH₂)₁—CONH₂,        F₅S—(CH₂)₂—OH, F₅S—(CH₂)₃—OH and F₅S—CH₂—CHCl—(CH₂)₈—X¹, where M        stands for H or an alkali metal ion, preferably Li⁺, Na⁺ or K⁺,        or NH₄ ⁺, and X¹ stands for OH, OC(═O)CH₃, Br, C(═O)OC₂H₅,        C(═O)CH₃, are excluded.        n in compounds of the formula I or II or III preferably stands        for a number from the range 4 to 28, particularly preferably a        number from the range 8 to 24.

In a preferred group of compounds of the formula I to be employed inaccordance with the invention or compounds of the formula II or IIIaccording to the invention, X stands for an anionic polar group selectedfrom —COOM, —SO₃M, —OSO₃M, —PO₃M₂, —OPO₃M₂,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—COOM, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—SO₃M,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—SO₃M, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—PO₃M₂,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—OPO₃M₂, where M stands for H or an alkalimetal ion, preferably Li⁺, Na⁺ or K⁺, or NH₄ ⁺, m stands for an integerfrom the range 1 to 1000, and o stands for an integer selected from 1,2, 3 or 4.

The preferred anionic groups here include, in particular, —COOM, —SO₃M,—OS₃M, as well as —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—COOM,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—SO₃M and —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—OSO₃M,where each individual one of these groups taken for itself may bepreferred.

In another, likewise preferred group of compounds of the formula I to beemployed in accordance with the invention or compounds of the formula IIor III according to the invention, X stands for a cationic polar groupselected from —NR¹R²R³+Z⁻, —PR¹R²R³⁺Z⁻,

-   -   where R stands for H or C₁₋₄-alkyl in any desired position,    -   Z⁻ stands for Cl⁻, Br⁻, I⁻, CH₃SO₃ ⁻;, CF₃SO₃ ⁻, CH₃PhSO₃ ⁻,        PhSO₃ ⁻, R¹, R² and R³ each, independently of one another, stand        for H, C₁₋₃₀-alkyl, Ar or —CH₂Ar and    -   Ar stands for an unsubstituted or mono- or polysubstituted        aromatic ring or fused ring system having 6 to 18 C atoms, in        which, in addition, one or two CH groups may be replaced by N.

The preferred cationic groups here include, in particular, —NR¹R²R³⁺Z⁻and

where each individual one of these groups taken for itself may bepreferred.

In a further preferred group of compounds of the formula I to beemployed in accordance with the invention or compounds of the formula IIor III according to the invention, X stands for a nonionic polar groupselected from —Cl, —Br, —I, —(OCH₂CH₂)_(m)—OH, —O-(glycoside)_(o),—(OCH₂CH₂)_(m)—OCH₂—CHOH—CH₂—OH, —(OCH₂CH₂)_(m)—OCH₂Ar(—NCO)_(p),—(OCH₂CH₂)_(m)—OAr(—NCO)_(p), —SiR¹R²Z, —SiR¹Z₂, —SiZ₃, —COZ,—(OCH₂CH₂)_(m)—SO₂CH═CH₂, —SO₂Z,

-   -   m stands for an integer from the range 0 to 1000,    -   n stands for 0 or 1 and    -   o stands for an integer from the range 1 to 10,    -   p stands for 1 or 2,    -   R¹ and R² each, independently of one another, stand for        C₁₋₃₀-alkyl,    -   Ar or —CH₂Ar and Ar stands for an unsubstituted, mono- or        polysubstituted aromatic ring or fused ring system having 6 to        18 C atoms, in which, in addition, one or two CH groups may be        replaced by C═O, and    -   glycoside stands for an etherified carbohydrate, preferably a        mono-, di-, tri- or oligoglucoside,    -   all Z each, independently of one another, stand for —H, —Cl, —F,        —NR¹R², —OR¹, —N-imidazolyl, and    -   Y stands for Cl or F.

The preferred nonionic polar groups here include, in particular,—(OCH₂CH₂)_(m)—OH and —O-(glycoside)_(o), where each individual one ofthese groups taken for itself may be preferred.

In addition, compounds of the formula I, II or III in which X stands fora polymerisable group selected from —(OCH₂CH₂)_(m)OCOCR═CH₂,—(OCH₂CH₂)_(m)—OCR═CH₂,

where m stands for an integer from the range 0 to 1000 and R and R¹stand for H or C₁₋₄-alkyl, may be preferred or preferably used inaccordance with the invention. These compounds are preferably convertedinto polymers having corresponding side chains, which may themselvesagain be employed in the sense according to the invention. The presentinvention also relates to the use of these polymers.

In addition, compounds in which X stands for an amphoteric groupselected from the functional groups of the acetyldiamines, theN-alkylamino acids, the betaines, the amine oxides or correspondingderivatives may be preferred or preferably used in accordance with theinvention. In preferred compounds of this class of substances, X is agroup selected from

The particularly preferred compounds here include the compounds shown inthe following table:

CF₃—O—(CH₂)₄—COOH; CF₃—O—(CH₂)₄—SO₃H; CF₃—O—(CH₂)₄—O—SO₃HCF₃—O—(CH₂)₅—COOH; CF₃—O—(CH₂)₅—SO₃H; CF₃—O—(CH₂)₅—O—SO₃HCF₃—O—(CH₂)₆—COOH; CF₃—O—(CH₂)₆—SO₃H; CF₃—O—(CH₂)₆—O—SO₃HCF₃—O—(CH₂)₇—COOH; CF₃—O—(CH₂)₇—SO₃H; CF₃—O—(CH₂)₇—O—SO₃HCF₃—O—(CH₂)₈—COOH; CF₃—O—(CH₂)₈—SO₃H; CF₃—O—(CH₂)₈—O—SO₃HCF₃—O—(CH₂)₉—COOH; CF₃—O—(CH₂)₉—SO₃H; CF₃—O—(CH₂)₉—O—SO₃HCF₃—O—(CH₂)₁₀—COOH; CF₃—O—(CH₂)₁₀—SO₃H; CF₃—O—(CH₂)₁₀—O—SO₃HCF₃—O—(CH₂)₁₁—COOH; CF₃—O—(CH₂)₁₁—SO₃H; CF₃—O—(CH₂)₁₁—O—SO₃HCF₃—O—(CH₂)₁₂—COOH; CF₃—O—(CH₂)₁₂—SO₃H; CF₃—O—(CH₂)₁₂—O—SO₃HCF₃—O—(CH₂)₁₃—COOH; CF₃—O—(CH₂)₁₃—SO₃H; CF₃—O—(CH₂)₁₃—O—SO₃HCF₃—O—(CH₂)₁₄—COOH; CF₃—O—(CH₂)₁₄—SO₃H; CF₃—O—(CH₂)₁₄—O—SO₃HCF₃—O—(CH₂)₁₅—COOH; CF₃—O—(CH₂)₁₅—SO₃H; CF₃—O—(CH₂)₁₅—O—SO₃HCF₃—O—(CH₂)₁₆—COOH; CF₃—O—(CH₂)₁₆—SO₃H; CF₃—O—(CH₂)₁₆—O—SO₃HCF₃—O—(CH₂)₁₇—COOH; CF₃—O—(CH₂)₁₇—SO₃H; CF₃—O—(CH₂)₁₇—O—SO₃HCF₃—O—(CH₂)₁₈—COOH; CF₃—O—(CH₂)₁₈—SO₃H; CF₃—O—(CH₂)₁₈—O—SO₃HCF₃—O—(CH₂)₁₉—COOH; CF₃—O—(CH₂)₁₉—SO₃H; CF₃—O—(CH₂)₁₉—O—SO₃HCF₃—O—(CH₂)₂₀—COOH; CF₃—O—(CH₂)₂₀—SO₃H; CF₃—O—(CH₂)₂₀—O—SO₃HCF₃—O—(CH₂)₂₁—COOH; CF₃—O—(CH₂)₂₁—SO₃H; CF₃—O—(CH₂)₂₁—O—SO₃HCF₃—O—(CH₂)₂₂—COOH; CF₃—O—(CH₂)₂₂—SO₃H; CF₃—O—(CH₂)₂₂—O—SO₃HCF₃—O—(CH₂)₂₃—COOH; CF₃—O—(CH₂)₂₃—SO₃H; CF₃—O—(CH₂)₂₃—O—SO₃HCF₃—O—(CH₂)₂₄—COOH; CF₃—O—(CH₂)₂₄—SO₃H; CF₃—O—(CH₂)₂₄—O—SO₃HSF₅—(CH₂)₄—COOH; SF₅—(CH₂)₄—SO₃H; SF₅—(CH₂)₄—O—SO₃H SF₅—(CH₂)₅—COOH;SF₅—(CH₂)₅—SO₃H; SF₅—(CH₂)₅—O—SO₃H SF₅—(CH₂)₆—COOH; SF₅—(CH₂)₆—SO₃H;SF₅—(CH₂)₆—O—SO₃H SF₅—(CH₂)₇—COOH; SF₅—(CH₂)₇—SO₃H; SF₅—(CH₂)₇—O—SO₃HSF₅—(CH₂)₈—COOH; SF₅—(CH₂)₈—SO₃H; SF₅—(CH₂)₈—O—SO₃H SF₅—(CH₂)₉—COOH;SF₅—(CH₂)₉—SO₃H; SF₅—(CH₂)₉—O—SO₃H SF₅—(CH₂)₁₀—COOH; SF₅—(CH₂)₁₀—SO₃H;SF₅—(CH₂)₁₀—O—SO₃H SF₅—(CH₂)₁₁—COOH; SF₅—(CH₂)₁₁—SO₃H;SF₅—(CH₂)₁₁—O—SO₃H SF₅—(CH₂)₁₂—COOH; SF₅—(CH₂)₁₂—SO₃H;SF₅—(CH₂)₁₂—O—SO₃H SF₅—(CH₂)₁₃—COOH; SF₅—(CH₂)₁₃—SO₃H;SF₅—(CH₂)₁₃—O—SO₃H SF₅—(CH₂)₁₄—COOH; SF₅—(CH₂)₁₄—SO₃H;SF₅—(CH₂)₁₄—O—SO₃H SF₅—(CH₂)₁₅—COOH; SF₅—(CH₂)₁₅—SO₃H;SF₅—(CH₂)₁₅—O—SO₃H SF₅—(CH₂)₁₆—COOH; SF₅—(CH₂)₁₆—SO₃H;SF₅—(CH₂)₁₆—O—SO₃H SF₅—(CH₂)₁₇—COOH; SF₅—(CH₂)₁₇—SO₃H;SF₅—(CH₂)₁₇—O—SO₃H SF₅—(CH₂)₁₈—COOH; SF₅—(CH₂)₁₈—SO₃H;SF₅—(CH₂)₁₈—O—SO₃H SF₅—(CH₂)₁₉—COOH; SF₅—(CH₂)₁₉—SO₃H;SF₅—(CH₂)₁₉—O—SO₃H SF₅—(CH₂)₂₀—COOH; SF₅—(CH₂)₂₀—SO₃H;SF₅—(CH₂)₂₀—O—SO₃H SF₅—(CH₂)₂₁—COOH; SF₅—(CH₂)₂₁—SO₃H;SF₅—(CH₂)₂₁—O—SO₃H SF₅—(CH₂)₂₂—COOH; SF₅—(CH₂)₂₂—SO₃H;SF₅—(CH₂)₂₂—O—SO₃H SF₅—(CH₂)₂₃—COOH; SF₅—(CH₂)₂₃—SO₃H;SF₅—(CH₂)₂₃—O—SO₃H SF₅—(CH₂)₂₄—COOH; SF₅—(CH₂)₂₄—SO₃H;SF₅—(CH₂)₂₄—O—SO₃H SF₅—CH═CH—(CH₂)₄—COOH; SF₅—CH═CH—(CH₂)₄—SO₃H;SF₅—CH═CH—(CH₂)₄—O—SO₃H SF₅—CH═CH—(CH₂)₅—COOH; SF₅—CH═CH—(CH₂)₅—SO₃H;SF₅—CH═CH—(CH₂)₅—O—SO₃H SF₅—CH═CH—(CH₂)₆—COOH; SF₅—CH═CH—(CH₂)₆—SO₃H;SF₅—CH═CH—(CH₂)₆—O—SO₃H SF₅—CH═CH—(CH₂)₇—COOH; SF₅—CH═CH—(CH₂)₇—SO₃H;SF₅—CH═CH—(CH₂)₇—O—SO₃H SF₅—CH═CH—(CH₂)₈—COOH; SF₅—CH═CH—(CH₂)₈—SO₃H;SF₅—CH═CH—(CH₂)₈—O—SO₃H SF₅—CH═CH—(CH₂)₉—COOH; SF₅—CH═CH—(CH₂)₉—SO₃H;SF₅—CH═CH—(CH₂)₉—O—SO₃H SF₅—CH═CH—(CH₂)₁₀—COOH; SF₅—CH═CH—(CH₂)₁₀—SO₃H;SF₅—CH═CH—(CH₂)₁₀—O—SO₃H SF₅—CH═CH—(CH₂)₁₁—COOH; SF₅—CH═CH—(CH₂)₁₁—SO₃H;SF₅—CH═CH—(CH₂)₁₁—O—SO₃H SF₅—CH═CH—(CH₂)₁₂—COOH; SF₅—CH═CH—(CH₂)₁₂—SO₃H;SF₅—CH═CH—(CH₂)₁₂—O—SO₃H SF₅—CH═CH—(CH₂)₁₃—COOH; SF₅—CH═CH—(CH₂)₁₃—SO₃H;SF₅—CH═CH—(CH₂)₁₃—O—SO₃H SF₅—CH═CH—(CH₂)₁₄—COOH; SF₅—CH═CH—(CH₂)₁₄—SO₃H;SF₅—CH═CH—(CH₂)₁₄—O—SO₃H SF₅—CH═CH—(CH₂)₁₅—COOH; SF₅—CH═CH—(CH₂)₁₅—SO₃H;SF₅—CH═CH—(CH₂)₁₅—O—SO₃H SF₅—CH═CH—(CH₂)₁₆—COOH; SF₅—CH═CH—(CH₂)₁₆—SO₃H;SF₅—CH═CH—(CH₂)₁₆—O—SO₃H SF₅—CH═CH—(CH₂)₁₇—COOH; SF₅—CH═CH—(CH₂)₁₇—SO₃H;SF₅—CH═CH—(CH₂)₁₇—O—SO₃H SF₅—CH═CH—(CH₂)₁₈—COOH; SF₅—CH═CH—(CH₂)₁₈—SO₃H;SF₅—CH═CH—(CH₂)₁₈—O—SO₃H SF₅—CH═CH—(CH₂)₁₉—COOH; SF₅—CH═CH—(CH₂)₁₉—SO₃H;SF₅—CH═CH—(CH₂)₁₉—O—SO₃H SF₅—CH═CH—(CH₂)₂₀—COOH; SF₅—CH═CH—(CH₂)₂₀—SO₃H;SF₅—CH═CH—(CH₂)₂₀—O—SO₃H SF₅—CH═CH—(CH₂)₂₁—COOH; SF₅—CH═CH—(CH₂)₂₁—SO₃H;SF₅—CH═CH—(CH₂)₂₁—O—SO₃H SF₅—CH═CH—(CH₂)₂₂—COOH; SF₅—CH═CH—(CH₂)₂₂—SO₃H;SF₅—CH═CH—(CH₂)₂₂—O—SO₃H SF₅—CH═CH—(CH₂)₂₃—COOH; SF₅—CH═CH—(CH₂)₂₃—SO₃H;SF₅—CH═CH—(CH₂)₂₃—O—SO₃H SF₅—CH═CH—(CH₂)₂₄—COOH; SF₅—CH═CH—(CH₂)₂₄—SO₃H;SF₅—CH═CH—(CH₂)₂₄—O—SO₃H SF₅—CH₂CHBr—(CH₂)₄—COOH;SF₅—CH₂CHBr—(CH₂)₄—SO₃H; SF₅—CH₂CHBr—(CH₂)₄—O—SO₃HSF₅—CH₂CHBr—(CH₂)₅—COOH; SF₅—CH₂CHBr—(CH₂)₅—SO₃H;SF₅—CH₂CHBr—(CH₂)₅—O—SO₃H SF₅—CH₂CHBr—(CH₂)₆—COOH;SF₅—CH₂CHBr—(CH₂)₆—SO₃H; SF₅—CH₂CHBr—(CH₂)₆—O—SO₃HSF₅—CH₂CHBr—(CH₂)₇—COOH; SF₅—CH₂CHBr—(CH₂)₇—SO₃H;SF₅—CH₂CHBr—(CH₂)₇—O—SO₃H SF₅—CH₂CHBr—(CH₂)₈—COOH;SF₅—CH₂CHBr—(CH₂)₈—SO₃H; SF₅—CH₂CHBr—(CH₂)₈—O—SO₃HSF₅—CH₂CHBr—(CH₂)₉—COOH; SF₅—CH₂CHBr—(CH₂)₉—SO₃H;SF₅—CH₂CHBr—(CH₂)₉—O—SO₃H SF₅—CH₂CHBr—(CH₂)₁₀—COOH;SF₅—CH₂CHBr—(CH₂)₁₀—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₀—O—SO₃HSF₅—CH₂CHBr—(CH₂)₁₁—COOH; SF₅—CH₂CHBr—(CH₂)₁₁—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₁—O—SO₃H SF₅—CH₂CHBr—(CH₂)₁₂—COOH;SF₅—CH₂CHBr—(CH₂)₁₂—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₂—O—SO₃HSF₅—CH₂CHBr—(CH₂)₁₃—COOH; SF₅—CH₂CHBr—(CH₂)₁₃—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₃—O—SO₃H SF₅—CH₂CHBr—(CH₂)₁₄—COOH;SF₅—CH₂CHBr—(CH₂)₁₄—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₄—O—SO₃HSF₅—CH₂CHBr—(CH₂)₁₅—COOH; SF₅—CH₂CHBr—(CH₂)₁₅—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₅—O—SO₃H SF₅—CH₂CHBr—(CH₂)₁₆—COOH;SF₅—CH₂CHBr—(CH₂)₁₆—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₆—O—SO₃HSF₅—CH₂CHBr—(CH₂)₁₇—COOH; SF₅—CH₂CHBr—(CH₂)₁₇—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₇—O—SO₃H SF₅—CH₂CHBr—(CH₂)₁₈—COOH;SF₅—CH₂CHBr—(CH₂)₁₈—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₈—O—SO₃HSF₅—CH₂CHBr—(CH₂)₁₉—COOH; SF₅—CH₂CHBr—(CH₂)₁₉—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₉—O—SO₃H SF₅—CH₂CHBr—(CH₂)₂₀—COOH;SF₅—CH₂CHBr—(CH₂)₂₀—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₀—O—SO₃HSF₅—CH₂CHBr—(CH₂)₂₁—COOH; SF₅—CH₂CHBr—(CH₂)₂₁—SO₃H;SF₅—CH₂CHBr—(CH₂)₂₁—O—SO₃H SF₅—CH₂CHBr—(CH₂)₂₂—COOH;SF₅—CH₂CHBr—(CH₂)₂₂—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₂—O—SO₃HSF₅—CH₂CHBr—(CH₂)₂₃—COOH; SF₅—CH₂CHBr—(CH₂)₂₃—SO₃H;SF₅—CH₂CHBr—(CH₂)₂₃—O—SO₃H SF₅—CH₂CHBr—(CH₂)₂₄—COOH;SF₅—CH₂CHBr—(CH₂)₂₄—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₄—O—SO₃H CF₃—O—(CH₂)₄—OH;CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₅—OH; CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₆—OH;CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₇—OH; CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₈—OH;CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₉—OH; CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₁₀—OH;CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₁₁—OH; CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₁₂—OH;CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₁₃—OH; CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₁₄—OH;CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₁₅—OH; CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₁₆—OH;CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₁₇—OH; CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₁₈—OH;CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₁₉—OH; CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₂₀—OH;CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₂₁—OH; CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₂₂—OH;CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₂₃—OH; CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—OH;CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ CF₃—O—(CH₂)₂₄—OH;CF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—OH; CF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₄—OH; SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₅—OH;SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₆—OH; SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₇—OH;SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₈—OH; SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₉—OH;SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₁₀—OH; SF₅—(CH₂)₁₀—(OCH₂CH₂)_(m)—OH;SF₅—CH₂)₁₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₁₁—OH;SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₁₂—OH; SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₁₃—OH;SF₅—(CH₂)₁₃—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₁₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₁₄—OH; SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₁₅—OH;SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₁₆—OH; SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₁₇—OH;SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₁₈—OH; SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₁₉—OH;SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₂₀—OH; SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₂₁—OH;SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₂₂—OH; SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—(CH₂)₂₃—OH;SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—OH; SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂SF₅—(CH₂)₂₄—OH; SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—OH;SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₄—OH;SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₅—OH;SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₆—OH;SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₇—OH;SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₈—OH;SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₉—OH;SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₀—OH;SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₁—OH;SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₂—OH;SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₃—OH;SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₄—OH;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₅—OH;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₆—OH;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₇—OH;SF₅—CH═CH—(CH₂)₁₇—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₈—OH;SF₅—CH═CH—(CH₂)₁₈—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₁₉—OH;SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₂₀—OH;SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₂₁—OH;SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₂₂—OH;SF₅—CH═CH—(CH₂)₂₂—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₂₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₂₃—OH;SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH═CH—(CH₂)₂₄—OH;SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OH;SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₄—OH;SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₅—OH;SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₆—OH;SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₇—OH;SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₈—OH;SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₉—OH;SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₀—OH;SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₁—OH;SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₂—OH;SF₅—CH₂CHBr—(CH₂)₁₂—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₃—OH;SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₄—OH;SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₅—OH;SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₆—OH;SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₇—OH;SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₈—OH;SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₁₉—OH;SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₂₀—OH;SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₂₁—OH;SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₂₂—OH;SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₂₃—OH;SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—SO₂—CH═CH₂ SF₅—CH₂CHBr—(CH₂)₂₄—OH;SF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—OH;SF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—SO₂—CH═CH₂CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)CF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p)SF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p) CF₃—O—(CH₂)₄—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₄—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₄—O- glucosideCF₃—O—(CH₂)₅—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₅—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₅—O-glucoside CF₃—O—(CH₂)₆—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₆—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₆—O- glucoside CF₃—O—(CH₂)₇—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₇—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₇—O- glucosideCF₃—O—(CH₂)₈—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₈—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₈—O-glucoside CF₃—O—(CH₂)₉—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₉—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₉—O- glucoside CF₃—O—(CH₂)₁₀—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₀—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₀—O- glucosideCF₃—O—(CH₂)₁₁—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₁—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₁—O-glucoside CF₃—O—(CH₂)₁₂—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₂—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₂—O- glucoside CF₃—O—(CH₂)₁₃—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₃—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₃—O- glucosideCF₃—O—(CH₂)₁₄—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₄—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₄—O-glucoside CF₃—O—(CH₂)₁₅—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₅—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₅—O- glucoside CF₃—O—(CH₂)₁₆—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₆—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₆—O- glucosideCF₃—O—(CH₂)₁₇—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₇—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₇—O-glucoside CF₃—O—(CH₂)₁₈—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₈—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₈—O- glucoside CF₃—O—(CH₂)₁₉—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₉—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₉—O- glucosideCF₃—O—(CH₂)₂₀—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₀—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₀—O-glucoside CF₃—O—(CH₂)₂₁—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₁—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₁—O- glucoside CF₃—O—(CH₂)₂₂—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₂—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₂—O- glucosideCF₃—O—(CH₂)₂₃—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₃—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₃—O-glucoside CF₃—O—(CH₂)₂₄—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₄—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₄—O- glucoside SF₅—(CH₂)₄—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₄—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₄—O-glucoside SF₅—(CH₂)₅—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₅—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₅—O-glucoside SF₅—(CH₂)₆—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₆—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₆—O-glucoside SF₅—(CH₂)₇—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₇—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₇—O-glucoside SF₅—(CH₂)₈—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₈—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₈—O-glucoside SF₅—(CH₂)₉—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₉—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₉—O-glucoside SF₅—(CH₂)₁₀—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₀—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₀—O-glucoside SF₅—(CH₂)₁₁—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₁—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₁—O-glucoside SF₅—(CH₂)₁₂—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₂—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₂—O-glucoside SF₅—(CH₂)₁₃—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₃—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₃—O-glucoside SF₅—(CH₂)₁₄—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₄—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₄—O-glucoside SF₅—(CH₂)₁₅—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₅—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₅—O-glucoside SF₅—(CH₂)₁₆—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₆—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₆—O-glucoside SF₅—(CH₂)₁₇—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₇—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₇—O-glucoside SF₅—(CH₂)₁₈—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₈—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₈—O-glucoside SF₅—(CH₂)₁₉—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₉—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₉—O-glucoside SF₅—(CH₂)₂₀—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₀—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₀—O-glucoside SF₅—(CH₂)₂₁—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₁—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₁—O-glucoside SF₅—(CH₂)₂₂—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₂—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₂—O-glucoside SF₅—(CH₂)₂₃—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₃—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₃—O-glucoside SF₅—(CH₂)₂₄—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₄—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₄—O-glucoside SF₅—CH═CH—(CH₂)₄—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₄—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₄—O- glucosideSF₅—CH═CH—(CH₂)₅—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₅—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₅—O- glucoside SF₅—CH═CH—(CH₂)₆—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₆—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₆—O- glucosideSF₅—CH═CH—(CH₂)₇—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₇—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₇—O- glucoside SF₅—CH═CH—(CH₂)₈—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₈—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₈—O- glucosideSF₅—CH═CH—(CH₂)₉—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₉—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₉—O- glucoside SF₅—CH═CH—(CH₂)₁₀—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₀—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₀—O- glucosideSF₅—CH═CH—(CH₂)₁₁—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₁—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₁—O- glucoside SF₅—CH═CH—(CH₂)₁₂—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₂—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₂—O- glucosideSF₅—CH═CH—(CH₂)₁₃—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₃—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₃—O- glucoside SF₅—CH═CH—(CH₂)₁₄—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₄—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₄—O- glucosideSF₅—CH═CH—(CH₂)₁₅—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₅—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₅—O- glucoside SF₅—CH═CH—(CH₂)₁₆—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₆—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₆—O- glucosideSF₅—CH═CH—(CH₂)₁₇—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₇—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₇—O- glucoside SF₅—CH═CH—(CH₂)₁₈—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₈—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₈—O- glucosideSF₅—CH═CH—(CH₂)₁₉—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₉—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₉—O- glucoside SF₅—CH═CH—(CH₂)₂₀—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₀—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₀—O- glucosideSF₅—CH═CH—(CH₂)₂₁—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₁—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₁—O- glucoside SF₅—CH═CH—(CH₂)₂₂—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₂—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₂—O- glucosideSF₅—CH═CH—(CH₂)₂₃—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₃—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₃—O- glucoside SF₅—CH═CH—(CH₂)₂₄—N⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₄—P⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₄—O- glucosideSF₅—CH₂CHBr—(CH₂)₄—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₄—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₄—O- glucoside SF₅—CH₂CHBr—(CH₂)₅—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₅—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₅—O- glucosideSF₅—CH₂CHBr—(CH₂)₆—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₆—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₆—O- glucoside SF₅—CH₂CHBr—(CH₂)₇—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₇—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₇—O- glucosideSF₅—CH₂CHBr—(CH₂)₈—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₈—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₈—O- glucoside SF₅—CH₂CHBr—(CH₂)₉—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₉—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₉—O- glucosideSF₅—CH₂CHBr—(CH₂)₁₀—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₀—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₀—O-glucoside SF₅—CH₂CHBr—(CH₂)₁₁—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₁—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₁—O-glucosideSF₅—CH₂CHBr—(CH₂)₁₂—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₂—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₂—O-glucoside SF₅—CH₂CHBr—(CH₂)₁₃—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₃—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₃—O-glucosideSF₅—CH₂CHBr—(CH₂)₁₄—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₄—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₄—O-glucoside SF₅—CH₂CHBr—(CH₂)₁₅—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₅—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₅—O-glucosideSF₅—CH₂CHBr—(CH₂)₁₆—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₆—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₆—O-glucoside SF₅—CH₂CHBr—(CH₂)₁₇—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₇—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₇—O-glucosideSF₅—CH₂CHBr—(CH₂)₁₈—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₈—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₈—O-glucoside SF₅—CH₂CHBr—(CH₂)₁₉—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₉—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₉—O-glucosideSF₅—CH₂CHBr—(CH₂)₂₀—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₀—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₀—O-glucoside SF₅—CH₂CHBr—(CH₂)₂₁—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₁—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₁—O-glucosideSF₅—CH₂CHBr—(CH₂)₂₂—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₂—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₂—O-glucoside SF₅—CH₂CHBr—(CH₂)₂₃—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₃—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₃—O-glucosideSF₅—CH₂CHBr—(CH₂)₂₄—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₄—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₄—O-glucoside

The compounds which can be used in accordance with the invention assurfactant are particularly suitable here for use as hydrophobicisingagents, for example for the surface modification of textiles, paper,glass, porous building materials or adsorbents, or as interfacemediators or emulsifiers, in particular for the preparation offluoropolymers, or as viscosity reducers or emulsifiers, in particularin paints, coatings or compositions for surface coating, or as foamstabilisers, in particular in compositions known as “fire-extinguishingfoams”, or in metalworking for covering electroplating baths to preventthe escape of caustic vapours, or as wetting agents in the production ofphotographic films and papers, or as flow-control agents in self-glossemulsions, or as fire-extinguishing agents, and for dirt-repellentfinishing.

In addition, the compounds which can be used in accordance with theinvention as surfactant are suitable for washing and cleaningapplications, in particular of textiles. The cleaning and polishing ofhard surfaces is also a potential area of application of the compoundswhich can be used in accordance with the invention as surfactant.Furthermore, the compounds which can be used in accordance with theinvention as surfactant can advantageously be employed in cosmeticproducts, such as, for example, foam baths and hair shampoos, or asemulsifiers in creams and lotions. A further area of application of thecompounds which can be used in accordance with the invention assurfactant is flotation, i.e. the recovery and separation of ores andminerals from dead rock. In addition, preferred compounds which can beused in accordance with the invention as surfactant can also be employedas emulsifiers in foods. Further fields of application are in metaltreatment, as leather auxiliaries, construction chemistry and in cropprotection.

The surfactants according to the invention are furthermore also suitableas antimicrobial active ingredient, in particular as reagents forantimicrobial surface modification. Of particular advantage for this useis the use of compounds of the formula I or II or III where X stands fora cationic polar group or a polymerisable group.

The compounds to be employed in accordance with the invention are, foruse, usually incorporated into appropriately designed compositions.Corresponding compositions, which are likewise a subject-matter of thepresent invention, comprise at least one surface-active compound havingat least one end group Y, where Y stands for CF₃O— or F₅S—, and acarrier which is suitable for the particular application and optionallyfurther specific active ingredients and optionally assistants.

Preferred compositions here are paint and coating compositions,fire-extinguishing compositions, lubricants, washing and cleaningcompositions, deicers or hydrophobicising compositions for textilefinishing or glass treatment. In a preferred variant of the invention,the compositions are hydrophobicising compositions for finishingtextiles and carpets.

For the hydrophobic finishing of textiles, hydrophobicising compositionsbased on polysiloxanes, fluorohydrocarbons or mixtures of aluminiumsalts or zirconium salts with paraffins are generally employed (cf. inthis respect “Handbuch der Textilhilfsmittel” [Handbook of TextileAssistants], A. Chwala, V. Anger, Verlag Ohemie, New York 1977, Chapter3.24 “Phobiermittel” [Phobicising Agents], pages 735 ff.). Thehydrophobic finishing of textiles, in particular in weather-protectionclothing, serves to make the latter either water-repellent orwaterproof. The hydrophobicising composition is applied to the fibres ofthe textiles, where it arranges itself in such a way that thehydrophobic moieties are perpendicular to the fibre surface. In thisway, the attempts by water to spread over the entire surface are greatlyreduced. Owing to the cohesion forces, the water adopts the sphericalshape and runs off the textile surface in the form of beads.

Further areas of application of compositions according to the inventionare paint and coating compositions, fire-extinguishing compositions(powders and foams), lubricants, washing and cleaning compositions andde-icers.

The compounds to be used in accordance with the invention can bepre-pared by methods known per se to the person skilled in the art fromthe literature. The aliphatic OCF₃ group can be obtained, for example,from alcohols via fluorodesulfuration of xanthogenates (K. Kanie, Y.Tanaka, K. Suzuki, M. Kuroboshi, T. Hiyama, Bull. Chem. Soc. Jpn. 2000,73, 471-484; P. Kirsch, Modern Fluoroorganic Chemistry; Synthesis,Reactivity, Applications, Wiley-VCH, Weinheim, 2004, pp. 67 ff., pp.1441ff.). The corresponding disclosure of the said method in the citedreferences thus expressly also belongs to the disclosure content of thepresent application. The introduction of the hydrophilic, anionic,cationic, reactive or polymerisable end group is possible via thecorresponding ω-OCF₃-alcohol by methods known to the person skilled inthe art. Examples are given in the following scheme:

The aliphatic SF₅ group can be added, for example, onto terminal doublebonds by the free-radical addition reaction of SF₅Cl or SF₅Br. Optionalsub-sequent dehydrohalogenation and hydrogenation allow variation of theend groups in accordance with the formulae IIIa, IIIb and IIIc. Thefirst two of these reaction steps are described in the literature (R.Winter, P. G. Nixon, G. L. Gard, D. H. Radford, N. R. Holcomb, D. W.Grainger, J. Fluorine Chem. 2001, 107, 23-30), as are catalytichydrogenations in the presence of an SF₅ function (P. Kirsch, M. Bremer,M. Heckmeier, K. Tarumi, Angew. Chem. 1999, 111, 2174-2178; Angew. Chem.Int. Ed. Engl. 1999, 38, 1989-1992). The corresponding disclosure of thesaid method in the cited references thus expressly also belongs to thedisclosure content of the present application. The introduction of thehydrophilic, reactive or polymerisable component is possible via thecorresponding ω-SF₅-alcohol by methods known to the person skilled inthe art. Examples are revealed by the following scheme:

The choice of suitable solvents and reaction conditions presents theperson skilled in the art with no difficulties at all (Organikum:Organisic-Chemisches Grundpraktikum [Practical Organic Chemistry: ABasic Course], 16th Edn., V E B Deutscher Verlag der Wissenschaften,Berlin, 1986).

The present invention therefore furthermore relates to a process for thepreparation of a compound of the formula i, characterised in thatfirstly a compound of the formula IVY-spacer-OH  IVis prepared and then, if X in the compound of the formula I is otherthan OH, converted into the compound of the formula I by modification ofthe OH group in a manner known per se,

-   a process for the preparation of a compound of the formula IIa,    characterised in that firstly a compound of the formula V    F₃CO—(CH₂)_(n)—OH  V    is prepared by conversion of a protected diol into the protected    monotrifluoromethoxyalcohol followed by deprotection, and is then,    if X in the compound of the formula Ia is other than OH, converted    into the compound of the formula IIa by modification of the OH group    in a manner known per se, and-   a process for the preparation of a compound of the formula IIIa,    IIIb or IIIc, characterised in that firstly a compound of the    formula IIIb in which X stands for OH is prepared and, if a compound    of the formula IIIa or IIIc is to be prepared, reacted by    elimination of hydrogen halide and, if a compound of the formula    IIIa is to be prepared, subsequent hydrogenation, and subsequently,    if X in the compound of the formula IIIa, IIIb or IIIc is other than    OH, the product is converted into the compound of the formula IIIa,    IIIb or IIIc by modification of the OH group in a manner known per    se.

The following examples explain the present invention in greater detailwithout restricting the scope of protection. In particular, thefeatures, properties and advantages, described in the examples, of thecompounds on which the relevant examples are based are also applicableto other substances and compounds which are not mentioned in detail, butfall within the scope of protection, unless stated otherwise elsewhere.Otherwise, the invention can be carried out in the entire scope claimedand is not restricted to the examples mentioned here.

EXAMPLES

List of abbreviations used:

Bn: benzyl DBH: 1,3-dibromo-5,5-dimethylhydantoin DMAP:4-(dimethylamino)pyridine Me: methyl THF: tetrahydrofuran

Example 1 ω-Trifluoromethoxyalkanols

-   1b: 80 mmol of 1a in 200 ml of THF are added dropwise at 0° C. to a    suspension of 95 mmol of NaH in 400 ml of THF. The mixture is heated    at 40° C. for 3 h, cooled again to 0° C., and 160 mmol of CS₂ are    added dropwise. After the mixture has been stirred at RT for a    further 1 h, 95 mmol of MeI are added dropwise at 0° C. The mixture    is stirred at RT for 18 h, subjected to conventional aqueous work-up    and chromatographed over silica gel.-   1c: 20 ml of 70% HF/pyridine are added slowly at −78° C. to a    suspension of 30 mmol of DBH (1,3-dibromo-5,5-dimethylhydantoin) in    30 ml of CH₂Cl₂ in a Teflon flask. A solution of 10 mmol of 1b in 30    ml of CH₂Cl₂ is added dropwise to this mixture at −78° C. The    mixture is stirred at −78° C. for 30 min, then allowed to come to    0° C. and hydrolysed using NaHSO₃ solution. The mixture is subjected    to aqueous work-up and chromatographed over silica gel.-   1d: 20 mmol of 1c in 400 ml of THF are hydrogenated in the presence    of 2g of 5% Pd/C at RT and a pressure of 4 bar until the uptake of    hydrogen is complete, The catalyst is filtered off via Celite, and    the product is purified by fractional distillation.

Corresponding derivatives can be prepared by variation of the alkylchain length of the starting materials.

Example 2

ω-Pentafluorosulfuranylalkanols

-   2a and 2b are prepared in accordance with the procedure in R.    Winter, P. G. Nixon, G. L. Gard, D. H. Radford, N. R. Holcomb, D. W.    Grainger, J. Fluorine Chem. 2001, 107, 23-30.-   2c-20 mmol of 2b in 400 ml of THF are hydrogenated in the presence    of 2 g of 5% Pd/C at RT and atmospheric pressure until the uptake of    hydrogen is complete. The catalyst is filtered off via Celite, and    the product is purified by fractional distillation.

Corresponding derivatives can be prepared by variation of the alkylchain length of the starting materials.

Example 3 Surface-Active Substances having Terminal Trifluoro-Methoxyand Pentafluorosulfuranyl Groups

-   4:120 mmol of PBr₃ are added to a solution of 100 mmol of 3 in 200    ml of toluene with ice-cooling, and the mixture is heated at reflux    for 3 h. The mixture is allowed to cool and subjected to    conventional aqueous work-up. The crude product is purified by    distillation.-   5: A mixture of 10 mmol of 4 and 30 ml of pyridine is heated at the    boil for 2 h. The mixture is evaporated under reduced pressure, and    the residue is precipitated using diethyl ether.-   6: A solution of 100 mmol of 3, 100 mmol of acrylic acid, 105 mmol    of di-cyclohexylcarbodiimide and 5 mmol of DMAP in 300 ml of THF is    stirred at RT for 18 h. The mixture is poured into water and    subjected to conventional aqueous work-up. The crude product is    purified by chromatography on silica gel (pentane).-   7: A mixture of 100 mmol of 4 and 150 mmol of dicyclohexylamine is    heated at 180° C. for 18 h. The product is distilled off, towards    the end under reduced pressure and at elevated temperature. The    crude product is purified by fractional distillation.-   8: 16 mg of H₂PtCl₆.6H₂O in 1 ml of iso-propanol are added to a    solution of 10 mmol of 7 and 20 mmol of triethoxysilane in 80 ml of    CH₂Cl₂, and the mixture is stirred at RT for 4 d. When the reaction    is complete, the product is purified by distillation.

Corresponding derivatives can be prepared by variation of the alkylchain length of the starting materials.

Example 4

Reaction of 5-pentafluorosulfuranylpentanol analogously to Example 3gives the corresponding pentafluorosulfuranyl derivatives. Correspondingderivatives can be prepared by variation of the alkyl chain length ofthe starting materials.

Example 5 ω-Trifluoromethoxyalkanesulfonate Example 5a Synthesis of10-Bromodecyl methyl dithiocarboxylate

200 ml of tetrahydrofuran (THF)+10.15 g of NaH (253 mmol, 1.2 eq) areintroduced into a nitrogen-flushed 1 l four-necked glass apparatus andcooled to −25° C. 50g of 6-bromo-1-decanol (211 mmol, 1 eq), mixed with100 ml of THF, are added dropwise with cooling. The mixture is stirredat RT for a further 120 min and subsequently again cooled to −25° C.Carbon disulfide (32.1 g; 421.6 mmol: 2 eq) is added dropwise, and themixture is subsequently stirred at 0° C. for a further 2.5 h. Methyliodide (35.9 g, 253 mmol; 1.2 eq) is added dropwise at −20° C. withcooling. The reaction mixture is slowly warmed to RT and stirred for afurther 24 h. After quenching using 10% NH₄Cl solution (200 ml), thephases are separated, and the organic phase is washed and evaporated todryness.

Example 5b Synthesis of 1-bromo-10-trifluoromethoxydecane

200 ml (7250 mmol, 61 eq) of HF/pyridine (65-70%) are added dropwise at−76° C. to a suspension of 1,3-dibromo-5,5-dimethylhydantoin (102g; 119mmol; 3 eq) in 420 ml of dichloromoethane, and stirring is continued.The xanthogenate from Example 5a (37g; 118.9 mmol; 1 eq) is then addeddropwise in 50 ml of dichloromethane. The reaction mixture is stirred atRT for 12 h. pH=10 is set using aqueous KOH solution. The reactionmixture is diluted with water and methyl t-butyl ether and subsequentlyfiltered The organic phase is dried and purified by columnchromatography using heptane.

Example 5c Synthesis of 10-trifluoromethoxydecane-1-sulfonic acid

6.8 g of bromide from Example 5b (22.35 mmol) and 3.7 g (29 mmol; 1.3eq) of sodium sulfite are dissolved in 40 ml of deionised water and 40ml of ethanol in a 250 ml one-necked flask, and the mixture is heated at100° C. for 20 h. The cooled reaction mixture is extracted with methylt-butyl ether/heptane (1:1). The aqueous phase is acidified (pH=0) andextracted with methyl t-butyl ether. The combined organic phases aredried over sodium sulfate and evaporated.

Example 5d Synthesis of Sodium 10-trifluoromethoxydecane-1-sulfonate

1.15 g (28.8 mmol; 1.3 eq) of NaOH are dissolved in 60 ml of ethanol andadded at RT to the sulfonic acid from Example 5c (6.8 g; 22.2 mmol; 1eq). After refluxing for 1 h, a colourless solid is obtained.

Sulfonates having various alkylene chain lengths can generally beobtained analogously to Example 5.

Example 6 ω-Pentafluorosulfuranyl-(ω-1)-chloroheptane-1-sulfonateExample 6a Synthesis of1-bromo-6-chloro-7-(pentafluorosulfuranyl)heptane

10g (56.5 mmol; 1 eq) of 7-bromoheptene are dissolved in 170 ml ofdichloromethane and cooled to −40C. SF₅Cl is condensed in a cold trapand passed into the apparatus as a gas. For activation, 2 ml of 1M Et₃Bsolution are added. The batch is yellow on introduction of the gas andbecomes colourless after addition of Et₃B. The addition is repeateduntil the batch no longer becomes colourless. The reaction mixture issubsequently stirred for a further two hours. The reaction mixture ishydrolysed and adjusted to pH 10. The organic phase is washed and dried.

Example 6b Synthesis of6-chloro-7-(pentafluorosulfuranyl)heptane-1-sulfonic acid

10g (29.4 mmol; 1 eq) of the product from Example Ga and 3.72 g (38.3mmol; 1.3 eq) of sodium sulfite are dissolved in 50 ml of deionisedwater and 50 ml of ethanol in a 250 ml one-necked flask and heated at100° C. for 15 h. After cooling, the reaction mixture is extracted witha 1:1 mixture of methyl t-butyl ether and heptane. The aqueous phase isacidified and extracted with methyl t-butyl ether. The combined organicphases are washed and evaporated to dryness.

Example 6c Synthesis of Sodium 6-chloro-7-(pentafluorosulfuranyl)heptane-1-sulfonate

10g (29.35 mmol; 1 eq) of sulfonic acid from Example 6b are suspended in130 ml of ethanol, and 1.4 9 (35.22 mmol; 1.2 eq) of sodium hydroxideare added. The reaction mixture is heated under reflux for 1 h. Thesolid is filtered off at RT.

Example 7 Synthesis of Sodium7-(pentafluorosulfuranyl)hept-6-ene-1-sulfonate:

10g (29.35 mmol; 1 eq) of sulfonic acid from Example 6b are suspended in400 ml of tetrahydrofuran in a 500 ml flask, and 11.74 g (293.5 mmol; 10eq) of sodium hydroxide are subsequently added. The reaction mixture isheated under reflux for 10 h, cooled and acidified, and the sulfonicacid is separated off from the aqueous phase by repeated extraction withmethyl t-butyl ether. The organic phase is subsequently washed andevaporated to dryness. The crude sulfonic acid is suspended in 100 ml ofethanol, 1.4 g (35.22 mmol; 1.2 eq) of sodium hydroxide are added, andthe mixture is heated at 97° C. for 1 h. After the suspension has beencooled, crystals deposit, which are filtered off and dried.

Example 8 Determination of the Biochemical Degradability

The biochemical degradability of the compounds is determined by theZahn-Wellens test in accordance with the publication by the EuropeanCommission: Classification, Packaging and Labelling of DangerousSubstances in the European Union, Part II—Test Methods, Annex V—Methodsfor the Determination of Physico-Chemical Properties, Toxicity andEcotoxicity, Part B, Biochemical Degradability—Zahn-Wellens Test (C.9.),January 1997, pages 353-357.

Batch volume: 1.5 l Activated sludge concentration: 1 g of solids/lOrigin of the sludge: Merck KGaA treatment plant, Darmstadt (notadapted) Amount of test substances used: about 100 to 200 mg/l as DOCAeration: with purified air Work-up of the samples: filtration(medium-hard filter) Determination of the DOC: by the difference methodusing a Dimatec instrument

Further details on the method can be obtained from the above-mentionedpublication or also from the OECD guideline for the testing ofchemicals, section 3, degradation and accumulation, method 302 B, pages1-8, adopted: 17 Jul. 1992, the contents of which in this respectexpressly belong to the disclosure content of the present application.

Besides the degradation of the compound, the degradation of thefluorine-containing groups is also observed per se in the test via afluoride determination:

Method: ion chromatography Instrument: Dionex 120 Detector type:conductivity detector Column: AS9HC Eluent: sodium carbonate solution, 9mmol/l Flow rate: 1 ml/min Literature: EN ISO 10304-2

Sodium 10-trifluoromethoxydecane-1-sulfonate from Example 5 isinvestigated. The measurement values are shown in the following tableand depicted graphically in FIG. 1.

Duration of the measurement Degradation (d) mg/l of free fluoride (DOC)in % 0 1.1 0 0.125 1.6 0 1 2.0 0.5 2 2.6 0.7 5 1.1 4.5 8 9.6 55 9 11.559 12 20.3 66 15 24.5 68 19 28.1 71 22 30.9 72 26 35.7 74 28 43.1 76

It can be seen that the compound is biologically degraded under theexperimental conditions with participation of the fluorinated CF₃Ogroup.

Example 9 Determination of the Surface Tension

Instrument: Krüss tensiometer (model K12) Temperature of the measurementsolutions: 20° C. Measurement module employed: ring Concentration of themeasurement solutions: about 0.5 to 3.0 g/l in deionised water

Further details on the method can be obtained from the publication bythe European Commission Classification, Packaging and Labelling ofDangerous Substances in the European Union, Part II—Test Methods, AnnexV—Methods for the Determination of Physico-Chemical Properties, Toxicityand Ecotoxicity, Part A, Surface Tension (A.5), January 1997, pages51-57, and from the OECD Guideline for the Testing of Chemicals, Section1, Physical-Chemical Properties, Method 115, pages 1-7, adopted: 27,July 95, the contents of which in this respect expressly belong to thedisclosure content of the present application.

Sodium 10-trifluoromethoxydecane-1-sulfonate from Example 5 isinvestigated in comparison with the classical hydrocarbon surfactantsodium decanesulfonate. The measurement values are shown in thefollowing table and depicted graphically in FIG. 2.

Concentration Concentration Surface of the solution of the solutiontension Sample g/l mol/l mN/m Example 5 0.5015 1.527E−03 59.95 1.00003.046E−03 52.55 2.0005 6.093E−03 42.61 Decane- 1.0020 4.101E−03 66.13sulfonic acid 2.0015 8.192E−03 57.70 Na salt 3.0010 1.228E−02 52.61

It can be seen that the surfactant according to the invention producesthe same surface tension at significantly lower concentration comparedwith the hydrocarbon surfactant. In addition, the curve extrapolationsuggests that the end value for the surfactant according to theinvention will also be significantly lower than for the hydrocarbonsurfactant.

LIST OF FIGURES

FIG. 1 shows the biochemical degradability of sodium10-trifluoromethoxydecane-1-sulfonate in the Zahn-Wellens test (DOCvalues) and the fluoride liberation during the test, in accordance withExample 8.

FIG. 2 shows the change in the surface tension of water as a function ofthe surfactant concentration for sodium10-trifluoromethoxydecane-1-sulfonate and sodium decanesulfonate inaccordance with Example 9.

1. A compound of formula IIa, IIb or IIcCF₃O—(CH₂)_(n)—X  IIaCF₃O—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IIbCF₃O—CH═CH—(CH₂)_((n−1))—X  IIc in which n is an integer from the range4 to 28, X is a cationic, nonionic, amphoteric or anionic polar group ora polymerizable group, and (Hal) is F, Cl, Br or I, or a correspondingsalt of a compound of the formula IIa, IIb or IIc, where X is not —COOH.2. A compound of formula IIIa, IIIb or IIIcF₅S—(CH₂)_(n)—X  IIIaF₅S—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IIIbF₅S—CH═CH—(CH₂)_((n−1))—X  IIIc in which n is an integer from the range1 to 30; (Hal) is F, Cl, Br or I; and X is (a) an anionic polar groupselected from —COOM, —SO₃M, —OSO₃M, —PO₃M₂, —OPO₃M₂,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—COOM, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—SO₃M,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)OSO₃M, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—PO₃M₂, and—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—OPO₃M₂, in which M is H, an alkali metal ion,or NH₄ ⁺, m is an integer from the range 1 to 1000, and o is an integerselected from 1, 2, 3 or 4; (b) a cationic polar group selected from—NR¹R²R³⁺Z⁻, —PR¹R²R³⁺Z⁻,

in which R is H or C₁₋₄-alkyl in any desired position, Z⁻ is Cl⁻, Br⁻,I⁻, CH₃SO₃ ⁻, CF₃SO₃ ⁻, CH₃PhSO₃ ⁻, PhSO₃ ⁻, R¹, R² and R³ are each,independently of one another, H, C₁₋₃₀-alkyl, Ar, or —CH₂Ar, and Ar isan unsubstituted or mono- or polysubstituted aromatic ring or fused ringsystem having 6 to 18 C atoms, in which, in addition, one or two CHgroups are each optionally replaced by N; (c) a polymerizable groupselected from —(OCH₂CH₂)_(m)OCOCR═CH₂, —(OCH₂CH₂)_(m)—OCR═CH₂,

in which m is an integer from the range 0 to 1000, and R and R¹ are eachH or C₁₋₄—; or (d) an amphoteric group selected from acetyldiamines, theN-alkylamino acids, betaines, amine oxides, and correspondingderivatives thereof; or a corresponding salt of a compound of formulaIIIa, IIIb or IIIc, with the proviso that when said compound if offormula IIIa or IIIc and X is an anionic polar group of (a), then n is4-28.
 3. A compound according to claim 1, wherein X is an anionic polargroup selected from —COOM, —SO₃M, —OSO₃M, —PO₃M₂, —OPO₃M₂,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—COOM, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—SO₃M,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—OSO₃M, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—PO₃M₂, and—(OCH₂CH₂)_(m)—O—(CH₂)_(o)OPO₃M₂, M is H, an alkali metal ion, or NH₄ ⁺,m is an integer from the range 1 to 1000, and o is an integer selectedfrom 1, 2, 3 or 4, wherein X is not —COOH.
 4. A compound according toclaim 1, wherein X is a cationic polar group selected from —NR¹R²R³⁺Z⁻,—PR¹R²R³⁺Z⁻,

R is H or C₁₋₄-alkyl in any desired position, Z⁻ is Cl⁻, Br⁻, I⁻, CH₃SO₃⁻, CF₃SO₃ ⁻, CH₃PhSO₃ ⁻, or PhSO₃ ⁻, R¹, R² and R³ are each,independently of one another, H, C₁₋₃₀-alkyl, Ar, or —CH₂Ar, and Ar isan unsubstituted or mono- or polysubstituted aromatic ring or fused ringsystem having 6 to 18 C atoms, in which, in addition, one or two CHgroups are each optionally replaced by N.
 5. A compound according toclaim 1, wherein X is a nonionic polar group selected from —Cl, —Br, —I,—(OCH₂CH₂)_(m)—OH, —O-(glycoside)_(o), —(OCH₂CH₂)_(m)—OCH₂—CHOH—CH₂—OH,—(OCH₂CH₂)_(m)—OCH₂Ar(—NCO)_(p), —(OCH₂CH₂)_(m)—OAr(—NCO)_(p), —SiR¹R²Z,—SiR¹Z₂, —SiZ₃, —COZ, —(OCH₂CH₂)_(m)—SO₂CH═CH₂, —SO₂Z, and

m is an integer from the range 0 to 1000, o is an integer from the range1 to 10, p is 1 or 2, R¹ and R² are each, independently of one another,C₁₋₃₀-alkyl, Ar, or —CH₂Ar, Ar is an unsubstituted or mono- orpolysubstituted aromatic ring or fused ring system having 6 to 18 Catoms, in which, in addition, one or two CH groups are each optionallyreplaced by N, glycoside is an etherified carbohydrate, all Z are each,independently of one another, —H, —Cl, —F, —NR¹R², —OR¹, or—N-imidazolyl, and Y is Cl or F.
 6. A compound according to claim 1,wherein X is a polymerizable group selected from—(OCH₂CH₂)_(m)OCOCR═CH₂, —(OCH₂CH₂)_(m)—OCR═CH₂,

m is an integer from the range 0 to 1000, and R and R¹ are each H orC₁₋₄-alkyl.
 7. A compound according to claim 1, wherein X is anamphoteric group selected from acetyldiamines, N-alkylamino acids,betaines, amine oxides, and corresponding derivatives thereof.
 8. Acomposition comprising at least one surface-active compound according toclaim 1, a suitable carrier, and optionally at least one further activeingredient.
 9. A composition according to claim 8, wherein saidcomposition is a paint or coating composition, fire-extinguishingcomposition, lubricant, washing or cleaning composition, de-icer orhydrophobicising composition for textile finishing or glass treatment.10. A compound according to claim 3, wherein M is H, Li⁺, Na⁺ or K⁺, orNH₄ ⁺.
 11. A compound according to claim 5, wherein glycoside is amono-, di-, tri- or oligoglucoside.
 12. A compound according to claim 1,wherein subscript n is a number from the range 8 to
 24. 13. A compoundaccording to claim 1, wherein said compound is of formula IIa.
 14. Acompound according to claim 1, wherein said compound is of formula IIb.15. A compound according to claim 1, wherein said compound is of formulaIIc.
 16. A compound according to claim 2, wherein said compound is offormula IIIa.
 17. A compound according to claim 2, wherein said compoundis of formula IIIb.
 18. A compound according to claim 2, wherein saidcompound is of formula IIIc.
 19. A compound according to claim 2,wherein X is an anionic polar group selected from —COOM, —SO₃M, —OSO₃M,—PO₃M₂, —OPO₃M₂, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—COOM,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—SO₃M, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—OSO₃M,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—PO₃M₂, and —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—OPO₃M₂,M is H, an alkali metal ion, or NH₄ ⁺, m is an integer from the range 1to 1000, and o is an integer selected from 1, 2, 3 or
 4. 20. A compoundaccording to claim 2, wherein X is a cationic polar group selected from—NR¹R²R³⁺Z⁻, —PR¹R²R³⁺Z⁻,

R is H or C₁₋₄-alkyl in any desired position, Z⁻ is Cl⁻, Br⁻, I⁻, CH₃SO₃⁻, CF₃SO₃ ⁻, CH₃PhSO₃ ⁻, PhSO₃ ⁻, R¹, R² and R³ are each, independentlyof one another, H, C₁₋₃₀-alkyl, Ar, or —CH₂Ar, and Ar is anunsubstituted or mono- or polysubstituted aromatic ring or fused ringsystem having 6 to 18 C atoms, in which, in addition, one or two CHgroups are each optionally replaced by N.
 21. A compound of formulaIIIa, IIIb or IIIcF₅S—(CH₂)_(n)—X  IIIaF₅S—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IIIbF₅S—CH═CH—(CH₂)_((n−1))—X  IIIc in which (Hal) is F, Cl, Br or I; and Xis a nonionic polar group selected from —Cl, —O-(glycoside)_(o),—(OCH₂CH₂)_(m)—OCH₂—CHOH—CH₂—OH, —(OCH₂CH₂)_(m)—OCH₂Ar(—NCO)_(p),—(OCH₂CH₂)_(m)—OAr(—NCO)_(p), —SiR¹R²Z, —SiR¹Z₂, —SiZ₃, —COZ,—(OCH₂CH₂)_(m)—SO₂CH═CH₂, —SO₂Z, and

m is an integer from the range 0 to 1000, n is an integer from the range8 to 24, o is an integer from the range 1 to 10, p is 1 or 2, R¹ and R²are each, independently of one another, C₁₋₃₀-alkyl, Ar, or —CH₂Ar, Aris an unsubstituted or mono- or polysubstituted aromatic ring or fusedring system having 6 to 18 C atoms, in which, in addition, one or two CHgroups are each optionally replaced by N, glycoside is an etherifiedcarbohydrate, all Z are each, independently of one another, —H, —Cl, —F,—NR¹R², —OR¹, or —N-imidazolyl, and Y is Cl or F.
 22. A compoundaccording to claim 2, wherein X is a polymerizable group selected from—(OCH₂CH₂)_(m)OCOCR═CH₂, —(OCH₂CH₂)_(m)—OCR═CH₂,

m is an integer from the range 0 to 1000, and R and R¹ are each H orC₁₋₄-alkyl.
 23. A compound according to claim 2, wherein X is anamphoteric group selected from acetyldiamines, N-alkylamino acids,betaines, amine oxides, and corresponding derivatives thereof.
 24. Acompound according to claim 2, wherein the subscript n is a number fromthe range 4 to
 28. 25. A compound according to claim 19, wherein M is H,Li⁺, Na⁺ or K⁺, or NH₄ ⁺.
 26. A compound according to claim 21, whereinglycoside is a mono-, di-, tri- or oligoglucoside.
 27. A compoundaccording to claim 24, wherein the subscript n is a number from therange 8 to
 24. 28. A compound according to claim 1, wherein X is a groupselected from

—[C(═O)—NH—(CH₂)₍₁₋₈₎]_((0 or 1))—N⁺R¹R²—O⁻, —NH—CH₂—COOM,—NH—CH₂—CH₂—COOM,

—[(C(═O)—NH—(CH₂)₍₁₋₈₎]_((0 or 1))—N⁺R¹R²—CH₂—COO⁻, or—C(═O)—NH—(CH₂)₁₋₃—N⁺R¹R²—CH₂—CH(OH)—CH₂—(O)_((0 or 1))—(S or P)O₃ ⁻,and R¹ and R² are each, independently of one another, C₁₋₈-alkyl.
 29. Acompound according to claim 2, wherein X is a group selected from

—[C(═O)—NH—(CH₂)₍₁₋₈₎]_((0 or 1))—N⁺R¹R²—O⁻, —NH—CH₂—COOM,—NH—CH₂—CH₂—COOM,

—[(C(═O)—NH—(CH₂)₍₁₋₈₎]_((0 or 1))—N⁺R¹R²—CH₂—COO⁻, or—C(═O)—NH—(CH₂)₁₋₃—N⁺R¹R²—CH₂—CH(OH)—CH₂—(O)_((0 or 1))—(S or P)O₃ ⁻,and R¹ and R² are each, independently of one another, C₁₋₈-alkyl.
 30. Acomposition comprising at least one surface-active compound according toclaim 2, a suitable carrier, and optionally at least one further activeingredient.
 31. A composition according to claim 30 wherein saidcomposition is a paint or coating composition, fire-extinguishingcomposition, lubricant, washing or cleaning composition, de-icer orhydrophobicising composition for textile finishing or glass treatment.32. A compound according to claim 1, wherein said compound is:CF₃—O—(CH₂)₄—SO₃H; CF₃—O—(CH₂)₄—O—SO₃H; CF₃—O—(CH₂)₅—SO₃H;CF₃—O—(CH₂)₅—O—SO₃H; CF₃—O—(CH₂)₆—SO₃H; CF₃—O—(CH₂)₆—O—SO₃H;CF₃—O—(CH₂)₇—COOH; CF₃—O—(CH₂)₇—SO₃H; CF₃—O—(CH₂)₇—O—SO₃HCF₃—O—(CH₂)₈—SO₃H; CF₃—O—(CH₂)₈—O—SO₃H; CF₃—O—(CH₂)₉—SO₃H;CF₃—O—(CH₂)₉—O—SO₃H; CF₃—O—(CH₂)₁₀—SO₃H; CF₃—O—(CH₂)₁₀—O—SO₃H;CF₃—O—(CH₂)₁₁—SO₃H; CF₃—O—(CH₂)₁₁—O—SO₃H; CF₃—O—(CH₂)₁₂—SO₃H;CF₃—O—(CH₂)₁₂—O—SO₃H; CF₃—O—(CH₂)₁₃—SO₃H; CF₃—O—(CH₂)₁₃—O—SO₃H;CF₃—O—(CH₂)₁₄—SO₃H; CF₃—O—(CH₂)₁₄—O—SO₃H; CF₃—O—(CH₂)₁₅—SO₃H;CF₃—O—(CH₂)₁₅—O—SO₃H; CF₃—O—(CH₂)₁₆—SO₃H; CF₃—O—(CH₂)₁₆—O—SO₃H;CF₃—O—(CH₂)₁₇—SO₃H; CF₃—O—(CH₂)₁₇—O—SO₃H CF₃—O—(CH₂)₁₈—SO₃H;CF₃—O—(CH₂)₁₈—O—SO₃H; CF₃—O—(CH₂)₁₉—SO₃H; CF₃—O—(CH₂)₁₉—O—SO₃H;CF₃—O—(CH₂)₂₀—SO₃H; CF₃—O—(CH₂)₂₀—O—SO₃H; CF₃—O—(CH₂)₂₁—SO₃H;CF₃—O—(CH₂)₂₁—O—SO₃H; CF₃—O—(CH₂)₂₂—SO₃H; CF₃—O—(CH₂)₂₂—O—SO₃H;CF₃—O—(CH₂)₂₃—SO₃H; CF₃—O—(CH₂)₂₃—O—SO₃H; CF₃—O—(CH₂)₂₄—SO₃H; orCF₃—O—(CH₂)₂₄—O—SO₃H.
 33. A compound according to claim 2, wherein saidcompound is: SF₅—(CH₂)₄—COOH; SF₅—(CH₂)₄—SO₃H, SF₅—(CH₂)₄—O—SO₃H;SF₅—(CH₂)₅—COOH SF₅—(CH₂)₅—SO₃H; SF₅—(CH₂)₅—O—SO₃H; SF₅—(CH₂)₆—COOH;SF₅—(CH₂)_(6—SO) ₃H; SF₅—(CH₂)₆—O—SO₃H; SF₅—(CH₂)₇—COOH;SF₅—(CH₂)₇—SO₃H; SF₅—(CH₂)₇—O—SO₃H; SF₅—(CH₂)₈—COOH; SF₅—(CH₂)₈—SO₃H;SF₅—(CH₂)₈—O—SO₃H; SF₅—(CH₂)₉—COOH; SF₅—(CH₂)₉—SO₃H; SF₅—(CH₂)₉—O—SO₃H;SF₅—(CH₂)₁₀—COOH; SF₅—(CH₂)₁₀—SO₃H; SF₅—(CH₂)₁₀—O—SO₃H;SF₅—(CH₂)₁₁—COOH; SF₅—(CH₂)₁₁—SO₃H; SF₅—(CH₂)₁₁—O—SO₃H;SF₅—(CH₂)₁₂—COOH; SF₅—(CH₂)₁₂—SO₃H; SF₅—(CH₂)₁₂—O—SO₃H;SF₅—(CH₂)₁₃—COOH; SF₅—(CH₂)₁₃—SO₃H; SF₅—(CH₂)₁₃—O—SO₃H;SF₅—(CH₂)₁₄—COOH; SF₅—(CH₂)₁₄—SO₃H; SF₅—(CH₂)₁₄—O—SO₃H;SF₅—(CH₂)₁₅—COOH; SF₅—(CH₂)₁₅—SO₃H; SF₅—(CH₂)₁₅—O—SO₃H;SF₅—(CH₂)₁₆—COOH; SF₅—(CH₂)₁₆—SO₃H; SF₅—(CH₂)₁₆—O—SO₃H;SF₅—(CH₂)₁₇—COOH; SF₅—(CH₂)₁₇—SO₃H; SF₅—(CH₂)₁₇—O—SO₃H;SF₅—(CH₂)₁₈—COOH; SF₅—(CH₂ ₁₈—SO₃H; SF₅—(CH₂)₁₈—O—SO₃H;SF₅—(CH₂)₁₉—COOH; SF₅—(CH₂)₁₉—SO₃H; SF₅—(CH₂)₁₉—O—SO₃H;SF₅—(CH₂)₂₀—COOH; SF₅—(CH₂)₂₀—SO₃H; SF₅—(CH₂)₂₀—O—SO₃H;SF₅—(CH₂)₂₁—COOH; SF₅—(CH₂)₂₁SO₃H; SF₅—(CH₂)₂₁—O—SO₃H; SF₅—(CH₂)₂₂—COOH;SF₅—(CH₂)₂₂—SO₃H; SF₅—(CH₂)₂₂—O—SO₃H; SF₅—(CH₂)₂₃—COOH;SF₅—(CH₂)₂₃—SO₃H; SF₅—(CH₂)₂₃—O—SO₃H; SF₅—(CH₂)₂₄—COOH;SF₅—(CH₂)₂₄—SO₃H; SF₅—(CH₂)₂₄—O—SO₃H; SF₅—CH═CH—(CH₂)₄—COOH;SF₅—CH═CH—(CH₂)₄—SO₃H; SF₅—CH═CH—(CH₂)₄—O—SO₃H; SF₅—CH═CH—(CH₂)₅—COOH;SF₅—CH═CH—(CH₂)₅—SO₃H; SF₅—CH═CH—(CH₂)₅—O—SO₃H; SF₅—CH═CH—(CH₂)₆—COOH;SF₅—CH═CH—(CH₂)₆—SO₃H; SF₅—CH═CH—(CH₂)₆—O—SO₃H; SF₅—CH═CH—(CH₂)₇—COOH;SF₅—CH═CH—(CH₂)₇—SO₃H; SF₅—CH═CH—(CH₂)₇—O—SO₃H; SF₅—CH═CH—(CH₂)₈—COOH;SF₅—CH═CH—(CH₂)₈—SO₃H; SF₅—CH═CH—(CH₂)₈—O—SO₃H; SF₅—CH═CH—(CH₂)₉—COOH;SF₅—CH═CH—(CH₂)₉—SO₃H; SF₅—CH═CH—(CH₂)₉—O—SO₃H; SF₅—CH═CH—(CH₂)₁₀—COOH;SF₅—CH═CH—(CH₂)₁₀—SO₃H; SF₅—CH═CH—(CH₂)₁₀—O—SO₃H;SF₅—CH═CH—(CH₂)₁₁—COOH; SF₅—CH═CH—(CH₂)₁₁—SO₃H;SF₅—CH═CH—(CH₂)₁₁—O—SO₃H; SF₅—CH═CH—(CH₂)₁₂—COOH;SF₅—CH═CH—(CH₂)₁₂—SO₃H; SF₅—CH═CH—(CH₂)₁₂—O—SO₃H;SF₅—CH═CH—(CH₂)₁₃—COOH; SF₅—CH═CH—(CH₂)₁₃—SO₃H;SF₅—CH═CH—(CH₂)₁₃—O—SO₃H; SF₅—CH═CH—(CH₂)₁₄—COOH;SF₅—CH═CH—(CH₂)₁₄—SO₃H; SF₅—CH═CH—(CH₂)₁₄—O—SO₃H;SF₅—CH═CH—(CH₂)₁₅—COOH; SF₅—CH═CH—(CH₂)₁₅—SO₃H;SF₅—CH═CH—(CH₂)₁₅—O—SO₃H; SF₅—CH═CH—(CH₂)₁₆—COOH;SF₅—CH═CH—(CH₂)₁₆—SO₃H; SF₅—CH═CH—(CH₂)₁₆—O—SO₃H;SF₅—CH═CH—(CH₂)₁₇—COOH; SF₅—CH═CH—(CH₂)₁₇—SO₃H;SF₅—CH═CH—(CH₂)₁₇—O—SO₃H; SF₅—CH═CH—(CH₂)₁₈—COOH;SF₅—CH═CH—(CH₂)₁₈—SO₃H; SF₅—CH═CH—(CH₂)₁₈—O—SO₃H;SF₅—CH═CH—(CH₂)₁₉—COOH; SF₅—CH═CH—(CH₂)₁₉—SO₃H;SF₅—CH═CH—(CH₂)₁₉—O—SO₃H; SF₅—CH═CH—(CH₂)₂₀—COOH;SF₅—CH═CH—(CH₂)₂₀—SO₃H; SF₅—CH═CH—(CH₂)₂₀—O—SO₃H;SF₅—CH═CH—(CH₂)₂₁—COOH; SF₅—CH═CH—(CH₂)₂₁—SO₃H;SF₅—CH═CH—(CH₂)₂₁—O—SO₃H; SF₅—CH═CH—(CH₂)₂₂—COOH;SF₅—CH═CH—(CH₂)₂₂—SO₃H; SF₅—CH═CH—(CH₂)₂₂—O—SO₃H;SF₅—CH═CH—(CH₂)₂₃—COOH; SF₅—CH═CH—(CH₂)₂₃—SO₃H;SF₅—CH═CH—(CH₂)₂₃—O—SO₃H; SF₅—CH═CH—(CH₂)₂₄—COOH;SF₅—CH═CH—(CH₂)₂₄—SO₃H; SF₅—CH═CH—(CH₂)₂₄—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₄—COOH; SF₅—CH₂CHBr—(CH₂)₄—SO₃H;SF₅—CH₂CHBr—(CH₂)₄—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₅—COOH;SF₅—CH₂CHBr—(CH₂)₅—SO₃H; SF₅—CH₂CHBr—(CH₂)₅—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₆—COOH; SF₅—CH₂CHBr—(CH₂)₆—SO₃H;SF₅—CH₂CHBr—(CH₂)₆—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₇—COOH;SF₅—CH₂CHBr—(CH₂)₇—SO₃H; SF₅—CH₂CHBr—(CH₂)₇—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₈—COOH; SF₅—CH₂CHBr—(CH₂)₈—SO₃H;SF₅—CH₂CHBr—(CH₂)₈—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₉—COOH;SF₅—CH₂CHBr—(CH₂)₉—SO₃H; SF₅—CH₂CHBr—(CH₂)₉—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₀—COOH; SF₅—CH₂CHBr—(CH₂)₁₀—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₀—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₁—COOH;SF₅—CH₂CHBr—(CH₂)₁₁—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₁—O—SO₃H; SF₅—CH₂CHBr—(CHA₂₁₂—COOH; SF₅—CH₂CHBr—(CH₂)₁₂—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₂—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₃—COOH; SF₅—CH₂CHBr—(CH₂)₁₃—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₃—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₄—COOH;SF₅—CH₂CHBr—(CH₂)₁₄—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₄—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₅—COOH; SF₅—CH₂CHBr—(CH₂)₁₅—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₅—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₆—COOH;SF₅—CH₂CHBr—(CH₂)₁₆—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₆—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₇—COOH; SF₅—CH₂CHBr—(CH₂)₁₇—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₇—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₈—COOH;SF₅—CH₂CHBr—(CH₂)₁₈—SO₃H; SF₅—CH₂CHBr—(CH₂)₁₈—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₉—COOH; SF₅—CH₂CHBr—(CH₂)₁₉—SO₃H;SF₅—CH₂CHBr—(CH₂)₁₉—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₀—COOH;SF₅—CH₂CHBr—(CH₂)₂₀—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₀—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₂₁—COOH; SF₅—CH₂CHBr—(CH₂)₂₁—SO₃H;SF₅—CH₂CHBr—(CH₂)₂₁—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₂—COOH;SF₅—CH₂CHBr—(CH₂)₂₂—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₂—O—SO₃H;SF₅—CH₂CHBr—(CH₂)₂₃—COOH; SF₅—CH₂CHBr—(CH₂)₂₃—SO₃H;SF₅—CH₂CHBr—(CH₂)₂₃—O—SO₃H; SF₅—CH₂CHBr—(CH₂)₂₄—COOH;SF₅—CH₂CHBr—(CH₂)₂₄—SO₃H; or SF₅—CH₂CHBr—(CH₂)₂₄—O—SO₃H.
 34. A compoundaccording to claim 1, wherein said compound is: CF₃—O—(CH₂)₄—OH;CF₃—O—(CH₂)₅—OH; CF₃—O—(CH₂)₆—OH; CF₃—O—(CH₂)₇—OH; CF₃—O—(CH₂)₈—H;CF₃—O—(CH₂)₉—OH; CF₃—O—(CH₂)₁₀—OH; CF₃—O—(CH₂)₁₁—OH; CF₃—O—(CH₂)₁₂—OH;CF₃—O—(CH₂)₁₃—OH; CF₃—O—(CH₂)₁₄—OH; CF₃—O—(CH₂)₁₅—OH; CF₃—O—(CH₂)₁₆—OH;CF₃—O—(CH₂)₁₇—OH; CF₃—O—(CH₂)₁₈—OH; CF₃—O—(CH₂)₁₉—OH; CF₃—O—(CH₂)₂₀—OH;CF₃—O—(CH₂)₂₁—OH; CF₃—O—(CH₂)₂₂—OH; CF₃—O—(CH₂)₂₃—OH; orCF₃—O—(CH₂)₂₄—OH.
 35. A compound according to claim 1, wherein saidcompound is: CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂;CF₃—O—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);CF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;CF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂; orCF₃—O—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p); wherein m is an integer fromthe range 0 to 1000, and p is 1 or
 2. 36. A compound according to claim2, wherein said compound is: SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂; SF₅—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₃(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂; SF₅—CH_(═CH—(CH)₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂; _(SF)₅—CH═CH—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH═CH—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₂—(OCH₂CH₂)_(m)—COCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₅—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₆—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₇—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₈—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₁₉—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₀—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₁—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₂—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—OCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₃—(OCH₂CH₂)_(m)—OAr(NCO)_(p);SF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCOCH═CH₂;SF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—OCH═CH₂; orSF₅—CH₂CHBr—(CH₂)₂₄—(OCH₂CH₂)_(m)—OAr(NCO)_(p); p1 wherein m is aninteger from the range 0 to 1000, and p is 1 or
 2. 37. A compoundaccording to claim 1, wherein said compound is: CF₃—O—(CH₂)₄—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₄—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₄—O-glucosiede;CF₃—O—(CH₂)₅—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₅—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₅—O-glucoside; CF₃—O—(CH₂)₆—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₆P⁺R¹R²R²Z⁻; CF₃—O—(CH₂)₆—O-glucosiede;CF₃—O—(CH₂)₇—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₇—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₇—O-glucosiede; CF₃—O—(CH₂)₈—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₈—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₈—O-glucosiede;CF₃—O—(CH₂)₉—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₉—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₉—O-glucosiede; CF₃—O—(CH₂)₁₀—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₀—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₀—O-glucosiede;CF₃—O—(CH₂)₁₁—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₁—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₁—O-glucosiede; CF₃—O—(CH₂)₁₂—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₂—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₂—O-glucosiede;CF₃—O—(CH₂)₁₃—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₃—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₇—O-glucosiede; CF₃—O—(CH₂)₁₄—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₄—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₄—O-glucosiede;CF₃—O—(CH₂)₁₅—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₅—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₅—O-glucosiede; CF₃—O—(CH₂)₁₆—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₆—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₆—O-glucosiede;CF₃—O—(CH₂)₁₇—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₇—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₇—O-glucosiede; CF₃—O—(CH₂)₁₈—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₈—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₈—O-glucosiede;CF₃—O—(CH₂)₁₉—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₁₉—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₁₉—O-glucosiede; CF₃—O—(CH₂)₂₀—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₀—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₀—O-glucosiede;CF₃—O—(CH₂)₂₁—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₁—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₁—O-glucosiede; CF₃—O—(CH₂)₂₂—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₂—P⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₂—O-glucosiede;CF₃—O—(CH₂)₂₃—N⁺R¹R²R³Z⁻; CF₃—O—(CH₂)₂₃—P⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₃—O-glucosiede; CF₃—O—(CH₂)₂₄—N⁺R¹R²R³Z⁻;CF₃—O—(CH₂)₂₄—P⁺R¹R²R³Z⁻; or CF₃—O—(CH₂)₂₄—O-glucoside.
 38. A compoundaccording to claim 2, wherein said compound is: SF₅—(CH₂)₄—N⁺R¹R²R³Z⁻;SF₅—(CH₂)₄—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₅—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₅—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₆—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₆—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₇—N⁺R¹R²R³Z⁻;SF₅—(CH₂)₇—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₈—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₈—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₉—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₉—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₀—N⁺R¹R²R³Z⁻;SF₅—(CH₂)—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₁—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₁—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₂—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₂—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₃—N⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₃—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₄N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₄—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₅—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₅—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₆—N⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₆—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₇—N⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₇—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₈—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₁₈—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₁₉—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₀—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₀—P ⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₁—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₁—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₂—N⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₂—P⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₃—N⁺R¹R²R³Z⁻; SF—(CH₂)₂₃—P⁺R¹R²R³Z⁻;SF₅—(CH₂)₂₄—N⁺R¹R²R³Z⁻; SF₅—(CH₂)₂₄—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₄—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₄—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₅—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₅—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₆—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₆—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₇—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₇—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₈—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₈—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₉—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₉—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₀—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₀—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₁—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₁—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₂—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₂—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₃—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₃—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₄—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₄—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₅—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)_(l5)—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₆—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₆—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₇—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₇—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₈—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₈—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₁₉—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₁₉—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₀—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₀—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₁—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₁—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₂—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₂—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₃—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₃—P⁺R¹R²R³Z⁻;SF₅—CH═CH—(CH₂)₂₄—N⁺R¹R²R³Z⁻; SF₅—CH═CH—(CH₂)₂₄—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₄—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₄—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₅—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₅—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₆—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₆—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₇—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₇—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₈—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₈—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₉—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₉—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₀—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₀—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₁—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₁—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₂—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₂—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₃—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₃—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₄—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₄—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₅—N⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₅—P⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₆—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₆—P⁺R¹R²R³ZSF₅—CH₂CHBr—(CH₂)₁₇—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₇—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₈—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₈—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₁₉—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₁₉—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₀—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₀—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₁—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₁—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₂—N⁺R¹R²R³Z⁻;SF₅—CH₂CHBr—(CH₂)₂₂—P⁺R¹R²R³Z ⁻; SF₅—CH₂CHBr—(CH₂)₂₃—N⁺R¹R²R³Z⁻;SF₅CH₂CHBr—(CH₂)₂₃—P⁺R¹R²R³Z⁻; SF₅—CH₂CHBr—(CH₂)₂₄—N⁺R¹R²R³Z⁻; orSF₅—CH₂CHBr—(CH₂)₂₄—P⁺R¹R²R³Z⁻.
 39. A compound according to claim 21,wherein said compound is: SF₅—(CH₂)₈—O-glucoside;SF₅—(CH₂)₉—O-glucoside; SF₅—(CH₂)₁₀—O-glucoside;SF₅—(CH₂)₁₁—O-glucoside; SF₅—(CH₂)₁₂—O-glucoside;SF₅—(CH₂)₁₃—O-glucoside; SF₅—(CH₂))₁₄—O-glucoside;SF₅—(CH₂)₁₅—O-glucoside; SF₅—(CH₂)₁₆—O-glucoside;SF₅—(CH₂)₁₇—O-glucoside; SF₅—(CH₂)₁₈—O-glucoside;SF₅—(CH₂)₁₉—O-glucoside; SF₅—(CH₂)₂₀—O-glucoside;SF₅—(CH₂)₂₁—O-glucoside; SF₅—(CH₂)₂₂—O-glucoside;SF₅—(CH₂)₂₃—O-glucoside; SF₅—(CH₂)₂₄—O-glucoside;SF₅—CH═CH—(CH₂)₈—O-glucoside; SF₅—CH═CH—(CH₂)₉—O-glucoside;SF₅—CH═CH—(CH₂)₁₀—O-glucoside; SF₅—CH═CH—(CH₂)₁₁—O-glucoside;SF₅—CH═CH—(CH₂)₁₂—O-glucoside; SF₅—CH═CH—(CH₂)₁₃—O-glucoside;SF₅—CH═CH—(CH₂)₁₄—O-glucoside; SF₅—CH═CH—(CH₂)₁₅—O-glucoside;SF₅—CH═CH—(CH₂)₁₆—O-glucoside; SF₅—CH═CH—(CH₂)₁₇—O-glucoside;SF₅—CH═CH—(CH₂)₁₈—O-glucoside; SF₅—CH═CH—(CH₂)₁₉—O-glucoside;SF₅—CH═CH—(CH₂)₂₀—O-glucoside; SF₅—CH═CH—(CH₂)₂₁—O-glucoside;SF₅—CH═CH—(CH₂)₂₂—O-glucoside; SF₅—CH═CH—(CH₂)₂₃—O-glucoside;SF₅—CH═CH—(CH₂)₂₄—O-glucoside; SF₅—CH₂CHBr—(CH₂)₈—O—glucoside;SF₅—CH₂CHBr—(CH₂)₉—O-glucoside; SF₅—CH₂CHBr—(CH₂)₁₀—-glucoside;SF₅—CH₂CHBr—(CH₂)₁₁—O-glucoside; SF₅—CH₂CHBr—(CH₂)₁₂—O-glucoside;SF₅—CH₂CHBr—(CH₂)₁₃—O-glucoside; SF₅—CH₂CHBr—(CH₂)₁₄—O-glucoside;SF₅—CH₂CHBr—(CH₂)₁₅—O—glucoside; SF₅—CH₂CHBr—(CH₂)₁₆—O-glucoside;SF₅—CH₂CHBr—(CH₂)₁₇—O-glucoside; SF₅—CH₂CHBr—(CH₂)₁₈—O-glucoside;SF₅—CH₂CHBr—(CH₂)₁₉—O-glucoside; SF₅—CH₂CHBr—(CH₂)₂₀—O-glucoside;SF₅—CH₂CHBr—(CH₂)₂₁—O-glucoside; SF₅—CH₂CHBr—(CH₂)₂₂—O -glucoside;SF₅—CH₂CHBr—(CH₂)₂₃—O-glucoside; or SF₅—CH₂CHBr—(CH₂)₂₄—O-glucoside. 40.A compound of formula IIa, IIb or IIcCF₃O—(CH₂)_(n)—X  IIaCF₃O—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IIbCF₃O—CH═CH—(CH₂)_((n−1))—X  IIc in which n is an integer from the range1 to 30, (Hal) is F, Cl, Br or I, X is (a) —COOM, —SO₃M, —OSO₃M, —PO₃M₂,—OPO₃M₂, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—COOM,—(OCH₂CH₂)_(m)—O—(CH₂)_(o)—SO₃M, —(OCH₂CH₂)_(m)—O—(CH₂)_(o)—OSO₃M,—(OCH₂CH₂)_(m—O—(CH) ₂)_(o)—PO₃M₂, or —(OCH₂CH₂)_(m—O—(CH)₂)_(o)—OPO₃M₂, M is H, an alkali metal ion, or NH₄ ⁺, m is an integerfrom the range 1 to 1000, and o is an integer selected from 1, 2, 3 or4, wherein X is not —COOH; (b) —NR¹R²R³⁺Z⁻, —PR¹R²R³⁺Z⁻,

R is H or C₁₋₄-alkyl in any desired position, Z⁻ is Cl⁻, Br⁻, I⁻, CH₃SO₃⁻, CF₃SO₃ ⁻, CH₃PhSO₃ ⁻, or PhSO₃ ⁻, R¹, R² and R³ are each,independently of one another, H, C₁₋₃₀-alkyl, Ar, or —CH₂Ar, and Ar isan unsubstituted or mono- or polysubstituted aromatic ring or fused ringsystem having 6 to 18 C atoms, in which, in addition, one or two CHgroups are each optionally replaced by N; (c) —Cl, —Br, —I,—(OCH₂CH₂)_(m)—OH, —O-(glycoside)_(o), —(OCH₂CH₂)_(m)—OCH₂—CHOH—CH₂—OH,—(OCH₂CH₂)_(m)—OCH₂Ar(—NCO)_(p), —(OCH₂CH₂)_(m)—OAr(—NCO)_(p), —SiR¹R²Z,—SiR¹Z₂, —SiZ₃, —COZ, —(OCH₂CH₂)_(m)—SO₂CH═CH₂, —SO₂Z, or

m is an integer from the range 0 to 1000, o is an integer from the range1 to 10, p is 1 or 2, R¹ and R² are each, independently of one another,C₁₋₃₀-alkyl, Ar, or —CH₂Ar, Ar is an unsubstituted or mono- orpolysubstituted aromatic ring or fused ring system having 6 to 18 Catoms, in which, in addition, one or two CH groups are each optionallyreplaced by N, glycoside is an etherified carbohydrate, all Z are each,independently of one another, —H, —Cl, —F, —NR¹R², —OR¹, or—N-imidazolyl, and Y is Cl or F; or (d) —(OCH₂CH₂)_(m)OCOCR═CH₂,—(OCH₂CH₂)_(m)—OCR═CH₂,

m is an integer from the range 0 to 1000, and R and R¹ are each H orC₁₋₄-alkyl; or a corresponding salt of a compound of the formula IIa,IIb or IIc.
 41. A compound of formula IIb or IIcCF₃O—CH₂—CH(Hal)-(CH₂)_((n−1))—X  IIbCF₃O—CH═CH—(CH₂)_((n−1))—X  IIc in which n is an integer from the range1 to 30, X is a cationic, nonionic, amphoteric or anionic polar group ora polymerizable group, and (Hal) is F, Cl, Br or I, or a correspondingsalt of a compound of the formula IIb or IIc.
 42. A process for thepreparation of a compound according to claim 13, said processcomprising: preparing a compound of formula VF₃CO—(CH₂)_(n)—OH  V by conversion of a protected diol into theprotected monotrifluoromethoxyalcohol followed by deprotection, and thenconverting the compound of formula V into said compound of formula IIaby modification of the OH group.
 43. A process for the preparation of acompound according to claim 2, said process comprising: preparing acompound of the formula F₅S—CH₂—CH(Hal)-(CH₂)_((n−1))—X in which X isOH, and, if a compound of formula IIIa or IIIc is to be prepared,reacted by elimination of hydrogen halide and, if a compound of formulaIIIa is to be prepared, subsequent hydrogenation, and subsequently theproduct is converted into the compound of formula IIIa, IIIb or IIIc bymodification of the OH group.